Crystallization Kinetics of Hybrid Perovskite Solar Cells

Author:

Wu Zhiwei1ORCID,Sang Shuyang1,Zheng Junjian1,Gao Qin,Huang Bin2,Li Feng3,Sun Kuan1,Chen Shanshan1ORCID

Affiliation:

1. MOE Key Laboratory of Low-grade Energy Utilization Technologies and Systems School of Energy & Power Engineering Chongqing University Chongqing 400044 China.

2. Jiangxi Provincial Key Laboratory of Functional Molecular Materials Chemistry Faculty of Materials Metallurgy and Chemistry Jiangxi University of Science and Technology Ganzhou 341000 China.

3. Laboratory of Advanced Materials Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials Fudan University 220 Handan Shanghai 200433 China.

Abstract

AbstractMetal halide perovskites (MHPs) are considered ideal photovoltaic materials due to their variable crystal material composition and excellent photoelectric properties. However, this variability in composition leads to complex crystallization processes in the manufacturing of Metal halide perovskite (MHP) thin films, resulting in reduced crystallinity and subsequent performance loss in the final device. Thus, understanding and controlling the crystallization dynamics of perovskite materials are essential for improving the stability and performance of PSCs (Perovskite Solar Cells). To investigate the impact of crystallization characteristics on the properties of MHP films and identify corresponding modulation strategies, we primarily discuss the relevant aspects of MHP crystallization kinetics, systematically summarize theoretical methods, and outline modulation techniques for MHP crystallization, including solution engineering, additive engineering, and component engineering, which helps highlight the prospects and current challenges in perovskite crystallization kinetics

Funder

Fundamental Research Funds for the Central Universities

National Natural Science Foundation of China

Publisher

Wiley

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