Controlled Radical Copolymerization toward Well‐Defined Fluoropolymers

Author:

Chen Kaixuan1,Guo Xing1,Chen Mao1ORCID

Affiliation:

1. Department of Macromolecular Science State Key Laboratory of Molecular Engineering of Polymers Fudan University Shanghai 200433 China

Abstract

AbstractIn the past 80 years, fluoropolymers have found broad applications in both industrial and academic settings, owing to their unique physicochemical properties. Copolymerizations of fluoroalkene feedstocks present an important avenue to obtain high‐performance materials by merging intrinsic attributes of fluorocarbons and great versatility of comonomers. Recently, while massive investigations have disclosed the great potentials of precisely synthesized polymers, researchers have made considerable efforts to approach well‐defined fluorinated copolymers. This minireview discusses challenges in controlled radical copolymerizations (CRCPs) of fluoroalkenes and provides a concise perspective on recent progress in CRCPs of fluoroalkenes (e.g., tetrafluoroethylene, chlorotrifluoroethylene, hexafluoropropene, perfluoroalkyl vinyl ethers) with non‐fluorinated vinyl comonomers, which have enabled on‐demand preparations of various main‐chain fluoropolymers with predefined molar masses, low dispersities, as well as regulable chemical compositions and sequences. The synthetic advantages of CRCPs will promote controlled and facile access to customized fluoropolymers for high‐tech applications such as batteries, coatings and so on.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Chemistry,Catalysis

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