Affiliation:
1. Key Laboratory of Green Chemistry & Technology of Ministry of Education College of Chemistry Sichuan University 29 Wangjiang Road Chengdu 610064 P. R. China
Abstract
AbstractChiral phosphonium salt catalysis, traditionally classified as a type of phase transfer catalysis, has proven to be a powerful strategy for the stereoselective preparation of diverse optically active molecules. However, there still remain numerous forbidding issues of reactivity and selectivity in such well‐known organocatalysis system. Accordingly, the development of new and high‐performance phosphonium salt catalysts with unique chiral backbones is highly desirable, yet challenging. This Minireview describes the prominent endeavours in the development of a new family of chiral peptide‐mimic phosphonium salt catalysts with multiple hydrogen‐bonding donors and their applications in a plethora of enantioselective synthesis during the past few years. Hopefully, this minireview will pave a way for further developing much more efficient and privileged chiral ligands/catalysts featuring exclusively catalytic ability in asymmetric synthesis.
Funder
National Natural Science Foundation of China
National Key Research and Development Program of China
Beijing National Laboratory for Molecular Sciences
Science Fund for Distinguished Young Scholars of Sichuan Province
Fundamental Research Funds for the Central Universities
Subject
General Chemistry,Catalysis
Cited by
10 articles.
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