Reductive Cross‐Coupling of a Vinyl Thianthrenium Salt and Secondary Alkyl Iodides-Reference-Cited by-同舟云学术

Reductive Cross‐Coupling of a Vinyl Thianthrenium Salt and Secondary Alkyl Iodides

Published:2023-11-23 Issue:52 Volume:62 Page:
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew Chem Int Ed

Author:

Lansbergen Beatrice¹²,Tewari Srija¹²,Tomczyk Ireneusz¹,Seemann Maik¹,Buchholz Henning Louis¹,Rippegarten Mike¹,Cieminski Daniel Chamier¹,Juliá Fabio¹,Ritter Tobias¹^ORCID

Affiliation:

1. Max-Planck-Institut für Kohlenforschung Kaiser-Wilhelm-Platz 1 45470 Mülheim an der Ruhr Germany

2. Institute of Organic Chemistry RWTH Aachen University Landoltweg 1 52074 Aachen Germany

Abstract

AbstractWe report the first reductive vinylation of alkyl iodides. The reaction uses a vinyl thianthrenium salt, a palladium catalyst, and an alkyl zinc intermediate formed in situ to trap the LnPdII(vinyl) complex formed after oxidative addition before it undergoes undesired homocoupling to form butadiene.

Publisher

Wiley

Subject

General Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202313659

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