Bypassing Ammonia: From N<sub>2</sub> to Nitrogen Heterocycles without N<sub>1</sub> Intermediates or Transition Metals-Reference-Cited by-同舟云学术

Bypassing Ammonia: From N₂ to Nitrogen Heterocycles without N₁ Intermediates or Transition Metals

Published:2024-04-11 Issue:21 Volume:63 Page:
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew Chem Int Ed

Author:

Weber Marco¹²,Kupfer Thomas¹²^ORCID,Arrowsmith Merle¹²^ORCID,Dewhurst Rian D.¹²^ORCID,Rang Maximilian¹²,Ritschel Benedikt¹²,Titlbach Sven³,Ernst Martin³^ORCID,Rodrigues Marieli O.⁴^ORCID,da Silva Júnior Eufrânio N.⁴^ORCID,Braunschweig Holger¹²^ORCID

Affiliation:

1. Institute for Inorganic Chemistry Julius-Maximilians-Universität Würzburg Am Hubland 97074 Würzburg Germany

2. Institute for Sustainable Chemistry & Catalysis with Boron Julius-Maximilians-Universität Würzburg Am Hubland 97074 Würzburg Germany

3. BASF SE Carl-Bosch-Straße 38 67056 Ludwigshafen am Rhein Germany

4. Department of Chemistry Institute of Exact Sciences Federal University of Minas Gerais, UFMG MG-31270-901 Belo Horizonte Brazil

Abstract

AbstractDiboradiazene compounds, derived in one step from the boron‐mediated reduction of dinitrogen (N2), were treated separately with sulfur and acetic anhydride, providing heterocyclic compounds that are BN isosteres of thiophene and 1,3‐oxazole, respectively. These simple reactions represent the final steps in two‐step routes to complex heterocycles from N2 that both circumvent the need for transition metal reagents and completely bypass the traditional intermediate ammonia.

Funder

Deutsche Forschungsgemeinschaft

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior

German Academic Exchange Service

Consejo Nacional para Investigaciones Científicas y Tecnológicas

Fundação de Amparo à Pesquisa do Estado de Minas Gerais

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202402777

Reference31 articles.

1. The continuing story of dinitrogen activation

2. Dinitrogen Coordination Chemistry: On the Biomimetic Borderlands

3. Homogeneous iron complexes for the conversion of dinitrogen into ammonia and hydrazine

4. Beyond Ammonia: Nitrogen–Element Bond Forming Reactions with Coordinated Dinitrogen