[Ph <sub>4</sub> P] <sup>+</sup> [Cu(CF <sub>2</sub> H) <sub>2</sub> ] <sup>−</sup> : A Powerful Difluoromethylating Reagent Inspired by Mechanistic Investigation-Reference-Cited by-同舟云学术

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[Ph ₄ P] ⁺ [Cu(CF ₂ H) ₂ ] ⁻ : A Powerful Difluoromethylating Reagent Inspired by Mechanistic Investigation

Published:2022-09-09 Issue:42 Volume:61 Page:
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew Chem Int Ed

Author:

Zhao Haiwei¹,Leng Xuebing B.¹,Zhang Wei²,Shen Qilong¹^ORCID

Affiliation:

1. Key Laboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry 345 Lingling Lu Shanghai 200032 China

2. Centre for Green Chemistry and Department of Chemistry University of Massachusetts Boston 100 Morrissey Boulevard Boston Massachusetts 02125 USA

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202210151

Reference70 articles.

1.

2. CF2H, a Hydrogen Bond Donor

3. Difluoromethyl Bioisostere: Examining the “Lipophilic Hydrogen Bond Donor” Concept

4. A survey of Hammett substituent constants and resonance and field parameters

5. Selected reviews for difluoromethylation:

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1. Pd-Catalyzed Divergent Site-Selective Difluoromethylation and Difluoromethylcarbonylation of Aryl Sulfonium Salts;ACS Catalysis;2024-08-28

2. Sulfone Electrophiles in Cross-Electrophile Coupling: Nickel-Catalyzed Difluoromethylation of Aryl Bromides;ACS Catalysis;2024-07-09

3. Introduction of the difluoromethyl group at the meta- or para-position of pyridines through regioselectivity switch;Nature Communications;2024-05-15

4. Difluoromethylated Difunctionalization of Alkenes under Visible Light;The Journal of Organic Chemistry;2024-02-01

5. Radical Brook Rearrangement Mediated Olefin Difunctionalization Involving α-Fluoroalkyl-α-silyl Methanols;Acta Chimica Sinica;2024

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