Cu(I)‐Glutathione Assembly Supported on ZIF‐8 as Robust and Efficient Catalyst for Mild CO<sub>2</sub> Conversions-Reference-Cited by-同舟云学术

Cu(I)‐Glutathione Assembly Supported on ZIF‐8 as Robust and Efficient Catalyst for Mild CO₂ Conversions

Published:2024-08-02 Issue:37 Volume:63 Page:
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew Chem Int Ed

Author:

Wang Wenjuan¹²^ORCID,Wang Tiansheng¹³,Chen Shuang⁴,Lv Ying⁴,Salmon Lionel³,Espuche Bruno⁵⁶,Moya Sergio⁵,Morozova Oksana⁵,Yun Yapei⁴,Di Silvio Desiré⁷,Daro Nathalie⁸,Berlande Murielle¹,Hapiot Philippe²,Pozzo Jean‐Luc¹,Yu Haizhu⁴,Hamon Jean‐René²,Astruc Didier¹^ORCID

Affiliation:

1. University of Bordeaux ISM, UMR CNRS N°5255 351 Cours de La Libération 33405 Talence Cedex France

2. Univ. Rennes, CNRS ISCR (Institut des Sciences Chimiques de Rennes) UMR 6226 35000 Rennes France

3. LCC, CNRS UPR 8241 & University of Toulouse 31077 Toulouse Cedex France

4. Department of Chemistry and Center for Atomic Engineering of Advanced Materials, Anhui Province Key Laboratory of Chemistry for Inorganic/Organic Hybrid Functionalized Materials Anhui University Hefei, Anhui 230601 People's Republic of China

5. Soft Matter Nanotechnology Lab CIC biomaGUNE Paseo Miramón 182 20014 Donostia-San Sebastián, Gipuzkoa Spain

6. POLYMAT, Applied Chemistry Department, Faculty of Chemistry University of the Basque Country, UPV/EHU Paseo Manuel de Lardizabal 3 Donostia-San Sebastián 20018 Spain

7. CIC biomaGUNE Paseo Miramón 194 20014 Donostia/San Sebastián, Gipuzkoa Spain

8. University of Bordeaux, CNRS Bordeaux INP, ICMCB, UMR 5026 33600 Pessac France

Abstract

AbstractThe Cu‐glutathione (GSH) redox system, essential in biology, is designed here as a supramacromolecular assembly in which the tetrahedral 18e Cu(I) center loses a thiol ligand upon adsorption onto ZIF‐8, as shown by EXAFS and DFT calculation, to generate a very robust 16e planar trigonal single‐atom Cu(I) catalyst. Synergy between Cu(I) and ZIF‐8, revealed by catalytic experiments and DFT calculation, affords CO2 conversion into high‐value‐added chemicals with a wide scope of substrates by reaction with terminal alkynes or propargyl amines in excellent yields under mild conditions and reuse at least 10 times without significant decrease in catalytic efficiency.

Funder

Anhui University

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202407430

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