A Multiresponsive Functional AIEgen for Spatiotemporal Pattern Control and All‐round Information Encryption

Author:

He Xinyuan1,Zhang Jianyu1,Liu Xinyue1,Jin Zhuwei1,Lam Jacky W. Y.1,Tang Ben Zhong123ORCID

Affiliation:

1. Department of Chemistry Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction Guangdong-Hongkong-Macou Joint Laboratory of Optoelectronic Magnetic Functional Materials The Hong Kong University of Science and Technology Clear Water Bay Kowloon Hong Kong China

2. Center for Aggregation-Induced Emission South China University of Technology Guangzhou 510640 China

3. School of Science and Engineering Shenzhen Institute of Aggregate Science and Technology The Chinese University of Hong Kong, Shenzhen Guangdong 518172 China

Abstract

AbstractFunctional materials with multi‐responsive properties and good controllability are highly desired for developing bioinspired and intelligent multifunctional systems. Although some chromic molecules have been developed, it is still challenging to realize in situ multicolor fluorescence changes based on a single luminogen. Herein, we reported an aggregation‐induced emission (AIE) luminogen called CPVCM, which can undergo a specific amination with primary amines to trigger luminescence change and photoarrangement under UV irradiation at the same active site. Detailed mechanistic insights were carried out to illustrate the reactivity and reaction pathways. Accordingly, multiple‐colored images, a quick response code with dynamic colors, and an all‐round information encryption system were demonstrated to show the properties of multiple controls and responses. It is believed that this work not only provides a strategy to develop multiresponsive luminogens but also develops an information encryption system based on luminescent materials.

Funder

National Natural Science Foundation of China

Innovation and Technology Commission

Natural Science Foundation of Guangdong Province

Publisher

Wiley

Subject

General Chemistry,Catalysis

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