A Recyclable and Scalable High‐Capacity Organic Battery

Author:

Chen Yuan12,Dai HuiChao1,Fan Kun12,Zhang Guoqun1,Tang Mi3,Gao Yanbo1,Zhang Chengyang1,Guan Linnan1,Mao Minglei1,Liu Huan12,Zhai Tianyou4,Wang Chengliang12ORCID

Affiliation:

1. School of Integrated Circuits School of Optical and Electronic Information Wuhan National Laboratory for Optoelectronics (WNLO) Huazhong University of Science and Technology Wuhan 430074 China

2. Wenzhou Advanced Manufacturing Institute Huazhong University of Science and Technology Wenzhou 325035 China

3. Hubei Key Laboratory of Polymer Materials School of Materials Science and Engineering Hubei University Wuhan 430062 China

4. State Key Laboratory of Materials Processing and Die & Mould Technology School of Materials Science and Engineering Huazhong University of Science and Technology Wuhan 430074 China

Abstract

AbstractRedox organic electrode materials (OEMs) have attracted extensive attention for batteries due to the possibility to be designed with high performance. However, the practical application of OEMs requires rigor criteria such as low cost, recyclability, scalability and high performance etc. and hence seems still far away. Here, we demonstrate an OEM for high performance aqueous organic batteries. Quantification of the charge storage confirmed the storage of protons with fast reaction kinetics, thereby enabling the high performance at high mass loading. As a result, the laminated pouch cells delivered Ampere‐hour‐scale capacity with excellent cycling performance. Benefited from the small molecular nature and the stable both charged and discharged states, the electrodes can be recycled at any states of charge with high yields (more than 90 %). This work provides a substantial step in the practical applications of OEMs for the future sustainable batteries.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Chemistry,Catalysis

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