Zn‐Organic Batteries for the Semi‐Hydrogenation of Biomass Aldehyde Derivatives and Concurrently Enhanced Power Output

Author:

Xu Heng1,Xu Guanxing1,Huang Bingji1,Yan Jiabiao1,Wang Min2,Chen Lisong13ORCID,Shi Jianlin2ORCID

Affiliation:

1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes School of Chemistry and Molecular Engineering East China Normal University North Zhongshan Road 3663 Shanghai 200062 P. R. China

2. State Key Laboratory of High Performance Ceramics and Superfine Microstructures Shanghai Institute of Ceramics Chinese Academy of Sciences Ding-xi Road 1295 Shanghai 200050 P. R. China

3. Institute of Eco-Chongming Shanghai 202162 P. R. China

Abstract

AbstractElectricity generation and chemical productions are both critically important for the sustainable development of modern civilization. Here, a novel bifunctional Zn‐organic battery has been established for the concurrent enhanced electricity output and semi‐hydrogenations of a series of biomass aldehyderivatives, for the high value‐added chemical syntheses. Among them, the typical Zn‐furfural (FF) battery equipped with Cu foil‐supported edge‐enriched Cu nanosheets as cathodic electrocatalyst (Cu NS/Cu foil), provides a maximum current density and power density of 14.6 mA cm−2and 2.00 mW cm−2, respectively, and in the meantime, produces high value product, furfural alcohol (FAL). The Cu NS/Cu foil catalyst exhibits excellent electrocatalytic performance of ≈93.5 % conversion ratio and ≈93.1 % selectivity for FF semi‐hydrogenation at a low potential of ‐1.1 V vs. Ag/AgCl by using H2O as H source, and shows impressive performance for various biomass aldehyderivatives semi‐hydrogenation.

Funder

National Key Research and Development Program of China

Natural Science Foundation of Shanghai

Publisher

Wiley

Subject

General Chemistry,Catalysis

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3