Affiliation:
1. Institute of Chemical Research of Catalonia (ICIQ) The Barcelona Institute of Science and Technology Av. Països Catalans 16 43007 Tarragona Spain
2. Catalan Institution for Research and Advanced Studies (ICREA) Passeig Lluïs Companys 23 08010 Barcelona Spain
Abstract
AbstractHerein, we describe a catalytic intramolecular decarboxylative/desulfonylative sp3 allylation triggered by sulfinate salts under light irradiation. The reaction is likely enabled by a non‐classical, radical‐polar crossover mechanism, allowing rapid and reliable access to valuable allyl architectures from readily accessible precursors. The protocol is characterized by its operational simplicity and scalability, employing abundant, commercially available catalysts.
Funder
H2020 European Research Council
Subject
General Chemistry,Catalysis
Cited by
7 articles.
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