Halogen‐Imparted Reactivity in Lithium Carbenoid Mediated Homologations of Imine Surrogates: Direct Assembly of bis‐Trifluoromethyl‐β‐Diketiminates and the Dual Role of LiCH 2 I-Reference-Cited by-同舟云学术

Halogen‐Imparted Reactivity in Lithium Carbenoid Mediated Homologations of Imine Surrogates: Direct Assembly of bis‐Trifluoromethyl‐β‐Diketiminates and the Dual Role of LiCH 2 I

Published:2020-09-09 Issue:47 Volume:59 Page:20852-20857
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew. Chem. Int. Ed.

Author:

Ielo Laura¹,Castoldi Laura¹,Touqeer Saad¹,Lombino Jessica²³,Roller Alexander⁴,Prandi Cristina⁵,Holzer Wolfgang¹,Pace Vittorio¹⁵^ORCID

Affiliation:

1. University of Vienna Department of Pharmaceutical Chemistry Althanstrasse 14 1090 Vienna Austria

2. Fondazione Ri.MED Via Bandiera 11 90133 Palermo Italy

3. University of Palermo Department STEBICEF Via Archirafi 32 90123 Palermo Italy

4. University of Vienna X-Ray Structure Analysis Center Waehringerstrasse 42 1090 Vienna Austria

5. University of Turin Department of Chemistry Via P. Giuria 7 10125 Turin Italy

Publisher

Wiley

Subject

General Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202007954

Reference75 articles.

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2. The Electrophilic Nature of Carbenoids, Nitrenoids, and Oxenoids

3. Direct observation of a lithiated oxirane: a synergistic study using spectroscopic, crystallographic, and theoretical methods on the structure and stereodynamics of lithiated ortho-trifluoromethyl styrene oxide

4. For comprehensive reviews on carbenoids see:

5. Lithium Carbenoids

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