Unlocking the Chain‐Walking Process in Gold Catalysis**-Reference-Cited by-同舟云学术

Unlocking the Chain‐Walking Process in Gold Catalysis**

Published:2023-10-13 Issue:46 Volume:62 Page:
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew Chem Int Ed

Author:

Bhoyare Vivek W.¹,Tathe Akash G.¹,Gandon Vincent²,Patil Nitin T.¹^ORCID

Affiliation:

1. Department of Chemistry Indian Institute of Science Education and Research Bhopal Bhopal Bypass Road, Bhauri 462 066 Bhopal India

2. Institut de Chimie Moléculaire et des Matériaux d'Orsay (UMR CNRS 8182) Paris-Saclay University bâtiment Henri Moissan, 17 avenue des sciences 91400 Orsay France

Abstract

AbstractThe successful realization of gold‐catalyzed chain‐walking reactions, facilitated by ligand‐enabled Au(I)/Au(III) redox catalysis, has been reported for the first time. This breakthrough has led to the development of gold‐catalyzed annulation reaction of alkenes with iodoarenes by leveraging the interplay of chain‐walking and π‐activation reactivity mode. The reaction mechanism has been elucidated through comprehensive experimental and computational studies.

Publisher

Wiley

Subject

General Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202312786

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