Cobalt(II)‐Catalyzed C(sp3)−C(sp3) Coupling for the Direct Stereoselective Synthesis of 2‐Deoxy‐C‐Glycosides from Glycals-Reference-Cited by-同舟云学术

Cobalt(II)‐Catalyzed C(sp³)−C(sp³) Coupling for the Direct Stereoselective Synthesis of 2‐Deoxy‐C‐Glycosides from Glycals

Published:2023-04-13 Issue:22 Volume:62 Page:
ISSN:1433-7851
Container-title:Angewandte Chemie International Edition
language:en
Short-container-title:Angew Chem Int Ed

Author:

Zeng Mingjie¹²,Yu Changyue²,Wang Yibing²,Wang Jingjing²,Wang Jiang²³,Liu Hong¹²^ORCID

Affiliation:

1. China Pharmaceutical University 639 Longmian Avenue, Jiangning District Nanjing 211198 China

2. State Key Laboratory of Drug Research Shanghai Institute of Materia Medica Chinese Academy of Sciences 555 Zu Chong Zhi Road Shanghai 201203 China

3. Lingang Laboratory Shanghai 200031 China

Abstract

AbstractWe report a ligand‐controlled CoII‐catalyzed C(sp3)−C(sp3) coupling hydroalkylation for direct and β‐selective synthesis of 2‐deoxy‐C‐glycosides from glycals. This reaction proceeds by a radical pathway for alkyl halide activation and is β‐selective through ligand control. This approach may inspire the development of further stereoselective coupling reactions with potential application in the field of carbohydrates.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

General Chemistry,Catalysis

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/anie.202300424

Reference41 articles.

2. Recent Advances in Aryl C-Glycoside Synthesis

3. Recent Advances in the Chemical Synthesis of C-Glycosides

4. Methods for 2-Deoxyglycoside Synthesis

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