Affiliation:
1. University of Münster MEET Battery Research Center Corrensstraße 46 48149 Münster Germany
2. Helmholtz-Zentrum Berlin für Materialien und Energie GmbH (HZB) Albert-Einstein-Straße 15 12489 Berlin Germany
3. Paderborn University Department of Chemistry Warburger Str. 100 33098 Paderborn Germany
4. Helmholtz Institute Münster IEK-12 Forschungszentrum Jülich GmbH Corrensstraße 46 48149 Münster Germany
Abstract
AbstractFaradaic reactions including charge transfer are often accompanied with diffusion limitation inside the bulk. Conductive two‐dimensional frameworks (2D MOFs) with a fast ion transport can combine both—charge transfer and fast diffusion inside their porous structure. To study remaining diffusion limitations caused by particle morphology, different synthesis routes of Cu‐2,3,6,7,10,11‐hexahydroxytriphenylene (Cu3(HHTP)2), a copper‐based 2D MOF, are used to obtain flake‐ and rod‐like MOF particles. Both morphologies are systematically characterized and evaluated for redox‐active Li+ ion storage. The redox mechanism is investigated by means of X‐ray absorption spectroscopy, FTIR spectroscopy and in situ XRD. Both types are compared regarding kinetic properties for Li+ ion storage via cyclic voltammetry and impedance spectroscopy. A significant influence of particle morphology for 2D MOFs on kinetic aspects of electrochemical Li+ ion storage can be observed. This study opens the path for optimization of redox active porous structures to overcome diffusion limitations of Faradaic processes.
Funder
Ministerium für Innovation, Wissenschaft und Forschung des Landes Nordrhein-Westfalen
Subject
General Chemistry,Catalysis
Cited by
9 articles.
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