Efficient and Stable Tin‐Lead Mixed Perovskite Solar Cells Using Post‐Treatment Additive with Synergistic Effects

Author:

Ding Xingdong1,Yan Meng1,Chen Cheng1,Zhai Mengde1,Wang Haoxin1,Tian Yi1,Wang Linqin2,Sun Licheng2,Cheng Ming1ORCID

Affiliation:

1. Institute for Energy Research School of Energy and Power Engineering Jiangsu University 212013 Zhenjiang China

2. Center of Artificial Photosynthesis for Solar Fuels and Department of Chemistry School of Science Westlake University 310024 Hangzhou China

Abstract

AbstractInhibiting the oxidation of Sn2+ during the crystallization process of Sn−Pb mixed perovskite film is found to be as important as the oxidation resistance of precursor solution to achieve high efficiency, but less investigated. Considering the excellent reduction feature of hydroquinone and the hydrophobicity of tert‐butyl group, an antioxidant 2,5‐di‐tert‐butylhydroquinone (DBHQ) was introduced into Sn−Pb mixed perovskite films using an anti‐solvent approach to solve this problem. Interestingly, we find that DBHQ can act as function alterable additive during its utilization. On the one hand, DBHQ can restrict the oxidation of Sn2+ during the crystallization process, facilitating the fabrication of high‐quality perovskite film; on the other hand, the generated oxidation product 2,5‐di‐tert‐butyl‐1,4‐benzoquinone (DBBQ) can functionalize as defect passivator to inhibit the charge recombination. As a result, this synergetic effect renders the Sn−Pb mixed PSC a power conversion efficiency (PCE) up to 23.0 %, which is significantly higher than the reference device (19.6 %). Furthermore, the unencapsulated DBQH‐modified PSCs exhibited excellent long‐term stability and thermal stability, with the devices maintaining 84.2 % and 78.9 % of the initial PCEs after aging at 25 °C and 60 °C for 800 h and 120 h under N2 atmosphere, respectively. Therefore, the functional alterable strategy provides a novel cornerstone for high‐performance Sn−Pb mixed PSCs.

Funder

National Natural Science Foundation of China

Outstanding Youth Foundation of Jiangsu Province

Publisher

Wiley

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