Affiliation:
1. Innovation Center for Textile Science and Technology College of Textiles Donghua University Shanghai 201620 China
Abstract
AbstractElectrochemical nitrogen reduction reaction (eNRR) is promising in place of the Haber–Bosch process for artificial N2fixation. However, the high activity and selectivity of eNRR are challenging to achieve simultaneously due to the scaling relations. Such “leverage” between activity and selectivity has severely restricted eNRR. To overcome this bottleneck, the complementary design of electronic structures in multicomponent electrocatalysts has been recently pursued, aiming to maximize the advantages of each component and optimize the multistep reactions, which has stood at the cutting edge in this aspect. Here, we present a minireview of the design, performance, and mechanism of multicomponent electrocatalysts with complementary electronic structures. We particularly emphasize the interactions between N2and elements fromd‐,p‐, ands‐blocks, which are essential for understanding how these electrocatalysts are beyond the “leverage” between activity and selectivity.
Funder
National Natural Science Foundation of China
Ministry of Science and Technology of the People's Republic of China
Subject
General Chemistry,Catalysis
Cited by
17 articles.
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