Unprecedented POSS‐Linked 3D Covalent Organic Frameworks with 2‐Fold Interpenetrated scu or sqc Topology Regulated by Porphyrin Center for Photocatalytic CO2 Reduction

Author:

Gao Ying1,Li Senzhi1,Gong Lei2,Li Jing3,Qi Dongdong1,Liu Naifang1,Bian Yongzhong14ORCID,Jiang Jianzhuang14

Affiliation:

1. Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry and Chemical Engineering, School of Chemistry and Biological Engineering University of Science and Technology Beijing Beijing 100083 China

2. National University of Singapore (Suzhou) Research Institute 377 Lin Quan Street, Suzhou Industrial Park Suzhou, Jiangsu 215123 China

3. Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry Chinese Academy of Sciences Beijing 100190 China

4. Daxing Research Institute, Beijing Advanced Innovation Center for Materials Genome Engineering University of Science and Technology Beijing Beijing 100083 China

Abstract

AbstractThe synthesis and characterization of porphyrin center regulated three‐dimensional covalent organic frameworks (COFs) with 2‐fold interpenetrated scu or sqc topology have been investigated. These COFs exhibit unique structural features and properties, making them promising candidates for photocatalytic applications in CO2 reduction and artemisinin synthesis. The porphyrin center serves as an anchor for metal ions, allowing precise control over structures and functions of the frameworks. Furthermore, the metal coordination within the framework imparts desirable catalytic properties, enabling their potential use in photocatalytic reactions. Overall, these porphyrin center regulated metal‐controlled COFs offer exciting opportunities for the development of advanced materials with tailored functionalities.

Funder

Postdoctoral Research Foundation of China

National Natural Science Foundation of China

Publisher

Wiley

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