Cooperation of Different Active Sites to Promote CO2 Electroreduction to Multi‐carbon Products at Ampere‐Level

Abstract

AbstractElectroreduction of CO2 to C2+ products provides a promising strategy for reaching the goal of carbon neutrality. However, achieving high selectivity of C2+ products at high current density remains a challenge. In this work, we designed and prepared a multi‐sites catalyst, in which Pd was atomically dispersed in Cu (Pd−Cu). It was found that the Pd−Cu catalyst had excellent performance for producing C2+ products from CO2 electroreduction. The Faradaic efficiency (FE) of C2+ products could be maintained at approximately 80.8 %, even at a high current density of 0.8 A cm−2 for at least 20 hours. In addition, the FE of C2+ products was above 70 % at 1.4 A cm−2. Experiments and density functional theory (DFT) calculations revealed that the catalyst had three distinct catalytic sites. These three active sites allowed for efficient conversion of CO2, water dissociation, and CO conversion, ultimately leading to high yields of C2+ products.