Noninnocence of the ligand atoms in iron-porphine: Chemical consequences of the delocalized electron spin
Author:
Affiliation:
1. Swedish Nuclear Fuel and Waste Management Co (SKB); Box 250, SE-101 24 Stockholm Sweden
Publisher
Wiley
Subject
Physical and Theoretical Chemistry,Condensed Matter Physics,Atomic and Molecular Physics, and Optics
Link
http://onlinelibrary.wiley.com/wol1/doi/10.1002/qua.25306/fullpdf
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1. Two States and Two More in the Mechanisms of Hydroxylation and Epoxidation by Cytochrome P450
2. Electronic Structure Makes a Difference: Cytochrome P-450 Mediated Hydroxylations of Hydrocarbons as a Two-State Reactivity Paradigm
3. Reactivity of High-Valent Iron–Oxo Species in Enzymes and Synthetic Reagents: A Tale of Many States
4. Two-State Reactivity as a New Concept in Organometallic Chemistry
5. Observed enhancement of the reactivity of a biomimetic diiron complex by the addition of water - mechanistic insights from theoretical modeling
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