Effect of GO‐TiO2 to waterborne epoxy resin on microstructure and anti‐corrosion properties

Author:

Wan Tao12,Wang Bo2ORCID,Wei Shicheng12,Yu Kailun12,Wang Yujiang2,Liang Yi2,Huang Wei3,Chen Hao2,Jiao Zhongyuan2

Affiliation:

1. Key Laboratory for Ecological Metallurgy of Multimetallic Mineral (Ministry of Education) Northeastern University Shenyang People's Republic of China

2. National Key Laboratory for Remanufacturing Army Academy of Armored Forces Beijing People's Republic of China

3. Department of Naval Architecture Engineering Naval University of Engineering Wuhan China

Abstract

AbstractTo enhance the anti‐corrosion of the waterborne epoxy resin coating, we filled GO‐TiO2 into the coating with ultrasound and stirring method. Results show that coatings rendered optimum properties at GO‐TiO2 content of 0.4 wt% with a hardness of 3H and rate of thermal weight loss reduce 8.3 wt%. After immersion for 30 days, coating exhibited water absorption ratio of merely 11.25% and open circuit potential of −0.871 V. After 1000 h of scratch‐neutral salt spray test, no obvious signs of corrosion were observed on surface. Moreover, Electrochemical results demonstrated that maximum impedance modulus of 0.4GO‐TiO2 coating was 2.18 × 106 Ω cm2, corresponding to superior corrosion resistance. What is more, anticorrosion mechanism was discussed. In conclusion, Filling GO‐TiO2 improved mechanical properties, thermal stability and corrosion resistance of waterborne epoxy resin coatings.

Funder

National Natural Science Foundation of China

Publisher

Wiley

Subject

Materials Chemistry,Polymers and Plastics,Surfaces, Coatings and Films,General Chemistry

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