Effects of substitutions in the equatorial position on the stabilities of pentacoordinated silicon anions of ClSiabc OCl− (a , b , c = H, F, Cl) from theoretical investigation
Author:
Affiliation:
1. Gansu Key Laboratory of Environmental Friendly Composites and Biomass Utilization, College of Chemical Engineering; Northwest Minzu University; Lanzhou Gansu China
Funder
Fundamental Research Funds for the Central Universities of China
Publisher
Wiley
Subject
General Chemistry
Link
http://onlinelibrary.wiley.com/wol1/doi/10.1002/jccs.201700421/fullpdf
Reference59 articles.
1. Pentacoordinated molecules. 52. A pseudorotational coordinate for five-coordinated silicon. Synthesis and molecular structure of cyclic anionic silicates isoelectronic with phosphoranes
2. Pentacoordinated molecules. 61. Synthesis and molecular structure of five-coordinated spirocyclic anionic silicates containing tert-butyl groups. Hydrogen-bonding effects
3. Pentacoordinated molecules. 62. Acyclic substituent effects on the molecular structure of cyclic-containing five-coordinated anionic silicates; a model for nucleophilic substitution at silicon
4. Pentacoordinate silicon compounds: Pseudorotation at silicon
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