Two New Prostaglandin‐Like Compounds from Callicarpa arborea Roxb and Their NLRP3 Inflammasome Activation Inhibitory Activity

Author:

Zeb Muhammad Aurang1,Ding Ling1,Wang Meng‐Ru1,Tu Wen‐Chao1,Li Xiao‐Li1,Zhang Xing‐Jie1,Xiao Wei‐Lie1ORCID

Affiliation:

1. Key Laboratory of Medicinal Chemistry for Natural Resource of Ministry of Education Yunnan Characteristic Plant Extraction Laboratory Yunnan Research & Development Centre for Natural Products School of Chemical Science and Technology and School of Pharmacy State Key Laboratory for Conservation and Utilization of Bio-Resources in Yunnan Yunnan University Kunming 650500 People's Republic of China

Abstract

AbstractTwo new prostaglandin‐like compounds callicarboric acids A−B (12), along with six known compounds (38) were isolated from the stems of Callicarpa arborea Roxb. Their structures were determined with the help of modern spectroscopic techniques such as NMR, UV, IR, HR‐ESI‐MS, ECD, and ORD with the assistance of quantum chemical calculations. Compound 1 exhibited remarkable anti‐NLRP3 inflammasome activation potential, demonstrating an IC50 value of 0.74 μM. Additionally, by reducing GSDMD‐NT production, inhibiting caspase‐1 activation, and suppressing IL‐1β secretion, it effectively mitigated NLRP3 inflammasome‐induced pyroptosis in J774A.1 cells. These findings indicate that compound 1 possesses the capability to be a valuable candidate for further research and development as an NLRP3 inflammasome inhibitor.

Funder

National Natural Science Foundation of China

Applied Basic Research Foundation of Yunnan Province

Program for Changjiang Scholars and Innovative Research Team in University

Publisher

Wiley

Subject

Molecular Biology,Molecular Medicine,General Chemistry,Biochemistry,General Medicine,Bioengineering

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