Development of a Lignin‐Based Carrier ‐ Citronella Oil Nanoemulsion and Its Utilization as an Herbicide against Specific Weed Species

Author:

Restu Witta Kartika1ORCID,Aryana Nurhani1,Septiyanti Melati1,Triwulandari Evi1,Sampora Yulianti1,Devy Yenni Apriliany1,Muryanto 1,Ghozali Muhammad1,Meliana Yenny1,Sondari Dewi2,Fatriasari Widya2,Nasir Mohamad Ibrahim Mohamad3,Hazwan Hussin Mohd.3,Ogino Chiaki4

Affiliation:

1. Research Center for Chemistry National Research and Innovation Agency (BRIN) Kawasan Puspiptek Serpong South Tangerang, Banten 15314 Indonesia

2. Research Center for Biomass and Bioproducts National Research and Innovation Agency (BRIN) Cibinong Science Center Jl. Raya Bogor Km. 46 Cibinong, West Java 16911 Indonesia

3. Materials Technology Research Group (MaTRec) School of Chemical Sciences Universiti Sains Malaysia 11800 Minden, Penang Malaysia

4. Department of Chemical Science and Engineering Kobe University 1-1 Rokkodaicho, Nada-ku Kobe 657-8501 Japan

Abstract

AbstractThis research aims to create an emulsion formulation utilizing lignin as a carrier and citronella oil for its application as a herbicide. The formulation composition includes lignin solution 55–62 %v/v, Tween 80 25 %w/v, propylene glycol 10 %w/v, and citronella oil 3–10 %w/v. The preparation steps involve preparing the oil phase by mixing tween 80 surfactant, propylene glycol, and citronella oil; preparing the aqueous phase by mixing lignin into distilled water at pH 12 with stirring; mixing the oil phase and the water phase accompanied by stirring at 5000–10000 rpm for 1–5 minutes until a stable solution is formed as a natural herbicide. The application outcomes revealed that the formulation successfully eliminated specific weeds within two to three days at the maximum concentration of 10 %, leaving no detectable herbicide residue after 7 and 15 days of treatment. The result demonstrates how green technology has the capacity to replace herbicides derived from chemicals, especially in the agricultural sector.

Publisher

Wiley

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