Transforming Pharmaceutical Synthesis with Sein‐E‐B Nanocomposite Photocatalyst through 1,4‐NAD(P)H Cofactor Regeneration and C‐N Bond Activation

Author:

Shukla Ravindra K.1,Yadav Rajesh K.1,Gole Vitthal L.2,Singhal Rajat3,Shahin Rehana1,Mishra Shaifali1,Singh Satyam1,Sharma Kanchan1,Baeg Jin‐Ook4,El‐Hiti Gamal A.5,Kumar Yadav Krishna67,Kumar Gupta Navneet3ORCID

Affiliation:

1. Department of Chemistry and Environmental Science Madan Mohan Malaviya University of Technology Gorakhpur U.P. 273010 India

2. Department of Chemical Engineering Madan Mohan Malaviya University of Technology Gorakhpur 273010 U.P. India

3. Centre for Sustainable Technologies Indian Institute of Science Gulmohar Marg, Mathikere Bengaluru 560012 India

4. Artificial Photosynthesis Research group Korea Research Institute of Chemical Technology, Yuseong-gu Daejeon 34114 Republic of Korea

5. Department of Optometry College of Applied Medical Sciences King Saud University Riyadh 11433 Saudi Arabia

6. Faculty of Science and Technology Madhyanchal Professional University Ratibad Bhopal 462044 India

7. Environmental and Atmospheric Sciences Research Group Scientific Research Center Al-Ayen University Thi-Qar Nasiriyah 64001 Iraq

Abstract

AbstractThe need for sunlight chemical renewal and contemporary organic transformation has fostered the advancement of environmentally friendly photocatalytic techniques. For the first time, we report on the novel crafting of a bright future with selenium‐infused Eosin‐B (Sein‐E‐B) nanocomposite photocatalysts in this work. The Sein‐E‐B nanocomposite materials were created using a hydrothermal process for solar chemical regeneration and organic transformation under visible light. The synthesized samples were subjected to UV‐DRS‐visible spectroscopy, FT‐IR, SEM, EDX, EIS and XRD analysis. The energy band gap of the Sein‐E‐B nanocomposite photocatalyst was measured using UV‐DRS, and the result was around 2.06 eV. to investigate the generated Sein‐E‐B catalytic activity as a nanocomposite for 1,4‐NADH/NADPH re‐formation and C−N bond activation. This novel photocatalyst offers a promising alternative for the regeneration of solar chemicals and C−N bond creation between pyrrole and aryl halides.

Funder

Indian Institute of Science

Publisher

Wiley

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