Affiliation:
1. Department of Materials Engineering and Convergence Technology Gyeongsang National University (GNU) Jinju 52828 South Korea
2. School of Material Science and Engineering (Ceramic Engineering) Gyeongsang National University (GNU) Jinju 52828 South Korea
3. School of Materials Science and Engineering University of Ulsan (UOU) Ulsan 44776 South Korea
4. PLS‐II Beamline Division Pohang Accelerator Laboratory (PAL) Pohang 37673 South Korea
Abstract
The layered δ‐MnO2 (dMO) is an excellent cathode material for rechargeable aqueous zinc‐ion batteries owing to its large interlayer distance (~0.7 nm), high capacity, and low cost; however, such cathodes suffer from structural degradation during the long‐term cycling process, leading to capacity fading. In this study, a Co‐doped dMO composite with reduced graphene oxide (GC‐dMO) is developed using a simple cost‐effective hydrothermal method. The degree of disorderness increases owing to the hetero‐atom doping and graphene oxide composites. It is demonstrated that layered dMO and GC‐dMO undergo a structural transition from K‐birnessite to the Zn‐buserite phase upon the first discharge, which enhances the intercalation of Zn2+ ions, H2O molecules in the layered structure. The GC‐dMO cathode exhibits an excellent capacity of 302 mAh g−1 at a current density of 100 mA g−1 after 100 cycles as compared with the dMO cathode (159 mAh g−1). The excellent electrochemical performance of the GC‐dMO cathode owing to Co‐doping and graphene oxide sheets enhances the interlayer gap and disorderness, and maintains structural stability, which facilitates the easy reverse intercalation and de‐intercalation of Zn2+ ions and H2O molecules. Therefore, GC‐dMO is a promising cathode material for large‐scale aqueous ZIBs.
Funder
National Research Foundation of Korea
Subject
Energy (miscellaneous),Waste Management and Disposal,Environmental Science (miscellaneous),Water Science and Technology,General Materials Science,Renewable Energy, Sustainability and the Environment
Cited by
1 articles.
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