Enhancement of electrical parameters of PANI—A conducting polymer with low concentration nanofiller for optoelectronic and electrical application

Author:

Kumar Tamilarasi1,Muthukrishnan Meena1,Thiagamani Senthil Muthu Kumar234ORCID,Khan Anish5,Althomali Raed H.6,Hashem Mohamed7

Affiliation:

1. Department of Physics S.T. Hindu College (Affiliated to Manonmaniam Sundaranar University, Abishekapatti, Tirunelveli‐627012) Nagercoil Tamil Nadu India

2. Department of Mechanical Engineering Kalasalingam Academy of Research and Education Krishnankoil Tamil Nadu India

3. Department of Mechanical Engineering INTI International University, PersiaranPerdana BBN Nilai Negeri Sembilan Malaysia

4. Centre for Advanced Composite Materials (CACM) Universiti Teknologi Malaysia Johor Bahru Johor Malaysia

5. Center of Excellence for Advanced Materials Research King Abdulaziz University Jeddah Saudi Arabia

6. Department of Chemistry Prince Sattam Bin Abdulaziz University, College of Arts and Science Saudi Arabia

7. Department of Dental Health College of Applied Medical Sciences, King Saud University Riyadh Saudi Arabia

Abstract

AbstractElectrical conductivity is emerging as one of the most essential material's qualities of the 21st century due to the lightning‐fast advancements in the electronics sector and the continuously improving electrical goods. As conductive materials are used in the majority of the modern items we use, including power sources, energy generating systems, electrical circuits, sensors, and many others, continuing advancement in this field is very crucial. The novelty of this work lies in the dispersion of ferrite nanoparticles, which was synthesized using egg albumen to enhance the electrical behavior of PANI polymer films. In this research work, a simple casting approach was used to ex situ polymerize aniline to fabricate ultrathin and flexible CuFe2O4 distributed PANI films for electrical conductivity applications. The combustion approach was used to produce the copper ferrite nanoparticles, while egg albumen was not only used as the fuel but also it was used a capping agent to control the size of ferrite NPs with a size much lower than that already reported. Studies on the structural, morphological, and electrical properties of pure and various weight percent of (1 , 3 , and 5 wt%) CuFe2O4 loaded PANI films were performed. Comparing the different films, the 5 wt% CuFe2O4 dispersed PANI films exhibited remarkable and greatly improved permittivity and electrical conductivity with low dielectric loss. This indicates the 5 wt% CuFe2O4 dispersed PANI films have the prospective uses in high‐tech industries where there is a need for flexible, thin, and lightweight high electrical conducting materials with lesser loss factor.

Funder

King Saud University

Prince Sattam bin Abdulaziz University

Publisher

Wiley

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