Twistocaloric Modeling of Elastomer Fibers and Experimental Validation

Author:

Mei Guangkai1,Li Jiatian1,Feng Danyang1,Qian Dong2,Liu Zunfeng1ORCID

Affiliation:

1. State Key Laboratory of Medicinal Chemical Biology, College of Chemistry and College of Pharmacy, Key Laboratory of Functional Polymer Materials, Frontiers Science Center for New Organic Matter Nankai University Tianjin 300071 China

2. Department of Mechanical Engineering University of Texas at Dallas Richardson Dallas TX 75080 USA

Abstract

AbstractThe twistocaloric effect is attributed to the change in entropy of the material driven by torsional stress. It is responsible for the torsional refrigeration of fiber materials that has been widely exploited as one of the solid‐state cooling techniques with high efficiency and low volume change rate. The lack of theories and mathematical models of twistocaloric effect, however, limits broad applications of torsional refrigeration. In this work, a twistocaloric model is established to capture the relationship between twist density and temperature variation of natural rubber fibers and thermoplastic elastomer yarns. An experimental setup consisting torsion actuator and torque sensor coupled with a temperature measurement system is built to validate the model. Using the Maxwell relationship, twistocaloric coefficient is measured by quantifying the thermal effect induced by torsion under shear strain. The experimental characterization of the twistocaloric effect in natural rubber fiber and thermoplastic elastomer yarn are consistent with the theoretical predictions.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Wiley

Subject

Materials Chemistry,Polymers and Plastics,Organic Chemistry

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