Hard–Soft Thermoset Alloy with Enhanced Toughness, Impact‐Resistance, and Electric Conductivity via Interpenetrated Dynamic Crosslinked Interface

Abstract

AbstractPolymer alloys (PAs) are mixtures of two or more types of polymers to enhance the properties of polymeric materials. However, thermosets with crosslinked structures are immiscible and cannot be prepared PAs. Herein, two immiscible covalent adaptable networks containing phenoxy carbamate bonds are explored as the typical polymeric materials to prepare the hard–soft thermoset alloy (HSTA) by the interpenetrated dynamic crosslinked interface (IDCI) to enhance the toughness. Specifically, two types of polyurethane covalent adaptable networks with either high stiffness (thermoset) or extensibility (elastomer) are prepared, respectively. The granules of thermoset and elastomer are mixed and hot‐pressed to prepare the HSTA. The HSTA shows improved mechanical properties with a toughness of 22.8 MJ m−3 which is 14 times higher than that of hard thermoset. In addition, the HSTA shows excellent impact‐resistance property after 1000 punctures. Moreover, the obtained HSTA via addition of carbon nanotubes can significantly decrease the electric resistance over six orders of magnitudes as compared to the blending method, which is due to the distribution of the carbon nanotubes at the interfaces of the two networks.