Author:
Neuenschwander Ulrich,Guignard Florian,Hermans Ive
Subject
General Energy,General Materials Science,General Chemical Engineering,Environmental Chemistry
Reference48 articles.
1. Sustainability in Catalytic Oxidation: An Alternative Approach or a Structural Evolution?
2. The characteristic lifetime τ of ROO⋅ radicals is given by 1/{2kterm[ROO⋅]}. Specifically for the case of α-pinene oxidation at 363 K, [ROO⋅] is already as high as 1.5×10−7 M [derived experimentally from Equation (9)] at 0.5 % conversion; hence τ is as low as 1-5 s, given 2kterm≤6×106 M−1 s−1. This ROO⋅ lifetime is much shorter than the timescale of several minutes over which [ROO⋅] changes significantly, such that a [ROO⋅] quasi-steady-state will be established immediately and maintained throughout the reaction.
Cited by
112 articles.
订阅此论文施引文献
订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献