MXenes as Electrocatalysts for Energy Conversion Applications: Advances and Prospects

Author:

El Ouardi Mohamed12,Ait Layachi Omar3,Channab Badr‐Eddine4ORCID,El Idrissi Ayoub4ORCID,BaQais Amal5ORCID,Arab Madjid2ORCID,Zbair Mohamed6ORCID,Saadi Mohamed1ORCID,Ait Ahsaine Hassan1ORCID

Affiliation:

1. Laboratory of Applied Materials Chemistry Faculty of Sciences Mohammed V University in Rabat Rabat 8007 Morocco

2. Université de Toulon Aix Marseille University CNRS IM2NP CS 60584 Toulon CEDEX 9, F‐83041 France

3. Laboratory of Physical Chemistry and Biotechnology of Biomolecules and Materials Faculty of Sciences and Technology Hassan II University of Casablanca Mohammedia 20650 Morocco

4. Laboratory of Materials, Catalysis & Natural Resources Valorization URAC 24 Faculty of Science and Technology Hassan II University Casablanca B.P. 146 Morocco

5. Department of Chemistry College of Science Princess Nourah Bint Abdulrahman University Riyadh 84428 Saudi Arabia

6. Institut de Science des Matériaux de Mulhouse (IS2M) Université de Haute‐Alsace CNRS IS2M UMR 7361 France Université de Strasbourg F‐68100 Mulhouse France

Abstract

Hydrogen as a potential future energy source provides a number of benefits in terms of sustainability, high energy density, and zero emissions. The production of hydrogen via water splitting is regarded as the cleanest and sustainable process. In contrast, fossil fuel combustion causes significant environmental problems through the production and release of secondary gases such as NOx, SO2, and CO2. It is vital to focus on reducing these harmful gases. CO2, a major pollutant produced by the combustion of fossil fuels and various human activities, plays a central role in the greenhouse effect and contributes to global warming. It is therefore imperative to actively eliminate and mitigate CO2 levels to preserve the global environment. MXenes and MXene‐based catalysts exhibit both outstanding hydrogen evolution reaction (HER) performance and CO2 reduction. In this review, recent progress is systematically examined and discussed in the preparation and utilization of MXenes as catalysts for HER and carbon dioxide reduction reaction (CO2RR). The discussion begins with a concise overview of the fabrication and characteristics of MXenes, followed by a comprehensive exploration of their efficacy as catalysts for HER and CO2RR.

Publisher

Wiley

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