Impact of Sequential N Ion Implantation on Extended Defects and Mg Distribution in Mg Ion‐Implanted GaN

Author:

Kano Emi1ORCID,Uzuhashi Jun2,Kobayashi Koki3,Ishikawa Kosuke3,Sawabe Kyosuke3,Narita Tetsuo4,Sierakowski Kacper5,Bockowski Michal35,Ohkubo Tadakatsu2,Kachi Tetsu1,Ikarashi Nobuyuki1ORCID

Affiliation:

1. Institute of Materials and Systems for Sustainability Nagoya University Nagoya Aichi 464‐8601 Japan

2. National Institute for Materials Science Tsukuba 305‐0047 Japan

3. Department of Electronics Graduate School of Engineering Nagoya University Nagoya Aichi 464‐8603 Japan

4. Toyota Central R&D Labs., Inc. Nagakute Aichi 480‐1192 Japan

5. Institute of High Pressure Physics Polish Academy of Sciences Sokolowska 29/37 01‐142 Warsaw Poland

Abstract

In Mg ion implantation doping of GaN, sequential N ion implantation reportedly changes Mg concentrations in the Mg ion‐implanted region and the underlying region after activation annealing. The impact of sequential N ion implantation on defects and Mg distribution after postimplantation annealing is investigated. The atomic‐resolution analyses show that, in the Mg ion‐implanted region, the N ion implantation increases the concentration of MgGa. It is thus concluded that the Mg soluble in GaN by Mg ion implantation is increased by N ion implantation. The rest of the Mg atoms agglomerate to form clusters on the extended defects, and their concentration is also increased by the N implantation. The coarsening of extended defects is suppressed by the N ion implantation: the defects in the Mg+N‐implanted sample are nanoscale interstitial‐type defects, and they do not grow or annihilate after annealing. This indicates that the N implantation changes the concentrations of interstitials.

Publisher

Wiley

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