Size Effects of Closed Encounter Ag Nanoshell Pairs for SERS Application

Abstract

Closed encounter Ag nanoshell pairs with remarkable improved plasmonic light enhancement in their gaps have been attracting much attention in the production of sensitivity SERS substrates. This work demonstrates the size effects of Ag nanoshell pairs on obtaining higher light intensity in their gaps. It is found that very complex light intensity changes occur in the gaps of Ag nanoshell pairs with their diameter enlargements ( $\text{diameters}>100$  nm). By the calculation of scattering efficiency and electric field vectors, the size-related light intensity changes in the gaps have been revealed and been concluded systematically. This work fills in the gaps of application of nanoshell pairs with larger sizes in SERS detectors and could guide the design of some other Ag nanoshell pair-based optical devices.