Low Energy Gamma Radiation Induced Effects on Ultrasonic Velocity and Acoustic Parameters in Polyvinylidene Fluoride Solution

Abstract

The modification of polyvinylidene fluoride (PVDF) polymer properties with irradiation is of interest as it possesses unique piezo-, pyro-, and ferroelectric properties. In this paper, we report the results of acoustic parameters of irradiated PVDF mixed with dimethylacetamide (DMAC) solution with low energy γ-source (Cs-137). The polymer solution covered with mica film assures only γ-ray passage and the duration was increased from 18 to 50 hours to achieve the higher dose rate. The dose rate was estimated using the strength of the radioactive source and the duration of the exposure. The ultrasonic velocity (v), density (ρ), and viscosity (η) of 0.2 wt% and 0.5 wt% PVDF dissolved in pure DMAC solution, irradiated with different dose rate were measured using ultrasonic interferometer (Mittal make), Pyknometer, and Oswald’s viscometer, respectively. It is observed that the values of v, ρ, and η change with dose rate. The acoustic parameters such as adiabatic compressibility (β), intermolecular free path length (Lf), acoustic impedance (Z), relative association (RA), ultrasonic attenuation (α/f2), and relaxation time (τ) are calculated using the experimental data. These results are interpreted in terms of the solute-solvent interaction in a polymer solution and scissoring chain damage.