Synthesis of 1,2,3-Triazole Derivatives and Its Evaluation as Corrosion Inhibitors for Carbon Steel

Author:

Resende Gabriel O.1,Teixeira Sara F.2,Figueiredo Igor F.1,Godoy Alexandre A.2,Lougon Dafne Júlia F.2,Cotrim Bruno A.1ORCID,Souza Flávia C. de2ORCID

Affiliation:

1. Instituto Federal de Educação Ciência e Tecnologia do Rio de Janeiro, Campus Rio de Janeiro, 20270-021 Rio de Janeiro, RJ, Brazil

2. Instituto Federal de Educação Ciência e Tecnologia do Rio de Janeiro, Campus São Gonçalo, 24425-005 São Gonçalo, RJ, Brazil

Abstract

Heterocyclic compounds containing the 1,2,3-triazole moiety can be synthesized through click-chemistry, which is rapid reactions with good yields allowing the synthesis of great derivatives diversity by making minor changes in the reagents. The products were obtained with good yields through a synthetic route which uses ready available nonexpensive commercial reagents and without any further purification of any product or intermediate. The carbon steel anticorrosive activity was tested through weight loss and electrochemical assays in acid media. It was observed relevant inhibition efficiency (> 90%) for inhibitors 1 and 2. From Langmuir isotherm, it was hypothesized the adsorption of inhibitors on the carbon steel surface might occur by physical and chemical interaction; however, the activation energy raised suggests a physisorption process for the interaction of the inhibitor on the carbon steel surface.

Funder

National Council of Technological and Scientific Development

Publisher

Hindawi Limited

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