A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water-Reference-Cited by-同舟云学术

A Ternary Catalytic System for the Room Temperature Suzuki-Miyaura Reaction in Water

Published:2013 Issue: Volume:2013 Page:1-8
ISSN:1537-744X
Container-title:The Scientific World Journal
language:en
Short-container-title:The Scientific World Journal

Author:

Silva Aires da Conceição¹,Senra Jaqueline Dias²,de Souza Andréa Luzia Ferreira³,Brum Malta Luiz Fernando¹

Affiliation:

1. Instituto de Química, Universidade Federal do Rio de Janeiro, CT Bloco A Lab 641, 21941-909 Rio de Janeiro, RJ, Brazil

2. Núcleo de Pesquisas de Produtos Naturais, Universidade Federal do Rio de Janeiro, CCS Bloco H, 21941-614 Rio de Janeiro, RJ, Brazil

3. Instituto de Química, Universidade Federal do Rio de Janeiro, 27930-560 Macaé, RJ, Brazil

Abstract

The formation of Pd(0) in the absence of any classical reducing agent in a medium containing Mg2+/Al3+layered double hydroxide (LDH) andN,N-dimethylformamide was evidenced. XRD analysis showed the presence of crystalline phases of palladium in the Pd/LDH composite. Suzuki-Miyaura reactions in aqueous medium were carried out at room temperature, and good yields were obtained with bromoarenes and iodoarenes using the ternary system LDH-Pd-CD (cyclodextrin) as catalyst.

Funder

CNPq

Publisher

Hindawi Limited

Subject

General Environmental Science,General Biochemistry, Genetics and Molecular Biology,General Medicine

Link

http://downloads.hindawi.com/journals/tswj/2013/456789.pdf

Reference27 articles.

1. Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds

2. Recent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles, 1995–1998

3. Dodecylsulfate Anion Embedded Layered Double Hydroxide Supported Nanopalladium Catalyst for the Suzuki Reaction