Synthesis and Oxygen Storage Capability of CeO2 Powders for Enhanced Photocatalytic Degradation of Acid Orange 7

Abstract

Acid Orange 7 (AO7) is one of the most common azo dyes; however, its strong azo bond makes them difficult to biologically degrade. We sought to degrade AO7 dye using CeO2 as a promising alternative photocatalyst. CeO2 powders were synthesized with alternative monoethanolamine (MEA), diethanolamine (DEA), and triethanolamine (TEA) as a precipitant by solvothermal process combined calcination in air. Compared to the oxygen storage capability of Blank-CeO2 (0.186 mmol O2/g), that of MEA-CeO2 synthesized in the presence of MEA as a precipitant increased by 21.0%, while that of DEA-CeO2 and TEA-CeO2 synthesized in the presence of DEA and TEA as precipitants were decreased. Importantly, such MEA-CeO2 exhibited the highest photocatalytic activity than Blank-, DEA-, and TEA-CeO2 in degradation of AO7 under simulated sunlight illumination, and the removal rate of AO7 by MEA-CeO2 could reach 98.3% within 100 min.