Affiliation:
1. Institute for Surface and Interface Science, Department of Chemistry, University of California, Irvine 92717, California, USA
Abstract
Laser induced charge transfer reactions of halogens in rare gas solids and liquids provide
a powerful means for the study of condensed phase dynamics. Many-body effects with
respect to both electronic and nuclear coordinates, and cooperative interactions with
radiation fields, are some of the studied phenomena that are highlighted in this article.The pertinence of these ionic reactions to chemistry in solids is demonstrated in
photodissociation studies of molecular halogens in rare gas matrices. The coexistence of
both delocalized and localized charge transfer states in solid xenon doped with atomic
halogens is presented and dynamical consequences—charge separation, self-trapping
and energy storage—are discussed. Static and dynamic solvent effects in liquid phase
harpoon reactions are considered. The characterization of cooperative excitations—
two-photon, two-electron transitions—in liquid solutions is presented.
Subject
Spectroscopy,Biochemistry,Atomic and Molecular Physics, and Optics
Cited by
63 articles.
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