Impact of Preparative pH on the Morphology and Photocatalytic Activity of BiVO4

Abstract

Adjusting pH with an ammonia solution during the synthesis, single-crystalline BiVO4has been prepared using Bi(NO3)3·5H2O and NH4VO3as starting materials through aqueous-phase precipitation at room temperature. The prepared samples are characterized by X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM). The impact of pH on structure, surface morphology, visible-light photocatalytic activity, and light absorption performance of BiVO4is explored and discussed. During the synthesis process, neither extremely acidic (low pH) nor basic (high pH) conditions are desirable for the formation of BiVO4in monoclinic phase. The highest photocatalytic performance on the degradation of a methylene blue solution is observed under pH=7.0for BiVO4in monoclinic scheelite, which is attributed to its small grain size and marked surface oxygen evolution ability.