Characteristic Features of Stone-Wales Defects in Single-Walled Carbon Nanotube; Adsorption, Dispersion, and Field Emission

Author:

Roh Seungkwang1,Lee Jongtaek2,Jang Mira2,Shin Mingyeong2,Ahn Juone2,Park Taehee2,Yi Whikun2

Affiliation:

1. Paju LCD Industrial Complex, Paju-city, Gyeonggi-do 413-779, Republic of Korea

2. Department of Chemistry, Hanyang University, Haengdang-dong 17, Seoul 133-791, Republic of Korea

Abstract

Adsorption behaviors of dodecanethiol (C12H25SH) molecules are investigated on the surface of single-walled carbon nanotubes (SWCNTs) with vibrational and X-ray photoelectron spectrometers. The active adsorption sites are proved as Stone-Wales (SW) defects (5–7 ring defects). The SW defect-removed SWCNTs formed by reacting nanotubes with allyl acrylate molecules are compared with pristine SWCNTs in dispersion and field emission. The former shows higher dispersion and field emission than the latter.

Funder

Korean Science and Engineering Foundation

Publisher

Hindawi Limited

Subject

General Materials Science

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