Investigation of Stereometric and Fractal Patterns of Spin-Coated LuMnO3 Thin Films

Author:

Marques Igor Hernandes Gomes12,Saraiva Matos Robert3ORCID,Romaguera-Barcelay Yonny4ORCID,Ţălu Ştefan5ORCID,Moreira Joaquim Agostinho6ORCID,Almeida Abilio6,de Cruz Javier Perez7,da Fonseca Filho Henrique Duarte124ORCID

Affiliation:

1. Materials Science and Engineering, Federal University of Amazonas, Manaus, Amazonas 69067-005, Brazil

2. Federal University of Amazonas, Laboratory of Nanomaterials Synthesis and Nanoscopy Physics Department, Amazonas 69067-005, Manaus, Brazil

3. Materials Science and Engineering, Federal University of Sergipe, São Cristóvão, Sergipe 49100-000, Brazil

4. Federal University of Amazonas, Physics Department, Manaus, Amazonas 69067-005, Brazil

5. Technical University of Cluj-Napoca, The Directorate of Research, Development and Innovation Management (DMCDI) Cluj County, Cluj-Napoca, Romania

6. Departamento de Física da Universidade do Porto, IFIMUP and IN-Institute of Nanoscience and Nanotechnology, Porto 4169-007, Portugal

7. Instituto de Soldadura e Qualidade, Av. Prof. Dr. Cavaco Silva, Porto Salvo 2740-120, Portugal

Abstract

In this paper, we have performed qualitative and quantitative analysis of LuMnO3 thin films surfaces, deposited by spin coating over Pt(111)/TiO2/SiO2/Si substrates, to evaluate their spatial patterns as a function of the film’s sintering temperature. Atomic force microscopy was employed to obtain topographic maps that were extensively analyzed via image processing techniques and mathematical tools. 3D (three-dimensional) topographical images revealed that films sintered at 650°C and 750°C presented the formation of smoother surfaces, while the film sintered at 850°C displayed a rougher surface with a root mean square roughness of ∼2.5 nm. On the other direction, the height distribution of the surface for all films has similar asymmetries and shape, although the film sintered using the highest temperature showed the lower density of rough peaks and a sharper peak shape. The advanced fractal parameters revealed that the film sintered at 850°C is dominated by low spatial frequencies, showing less spatial complexity, higher microtexture homogeneity, and uniform height distribution. These results suggest that the combination of stereometric and fractal parameters can be especially useful for identification of unique topographic spatial patterns in LuMnO3 thin films, helping in their implementation in technological applications, such as photovoltaic solar cells and information magnetic date storage and spintronic devices.

Publisher

Hindawi Limited

Subject

General Engineering,General Materials Science

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