Electric and Adsorption Characteristics of Nanocrystalline V-(N, He) Coatings

Author:

Guglya Alexey G.1ORCID,Kolobrodov Viktor G.1,Vasilenko Ruslan L.1

Affiliation:

1. NSC Kharkov Institute of Physics and Technology, National Academy of Sciences of Ukraine, 1, Akademicheskaya Street, 61108 Kharkov, Ukraine

Abstract

This paper studies the structure, temperature dependences of electric resistance, and adsorption properties of nanoporous three-component V-(N, He) coatings. The coatings were produced using the technique of ion beam assisted deposition, in particular, deposition of vanadium onto a titanium substrate simultaneously bombarding it with ions of 30 keV. It is shown, in contrast to V-N composites that have negative TCR (temperature coefficient of resistance), that the V-(N, He) coatings have negative TCR only in the temperature range of 250 to 350. A specific surface of pores and adsorption characteristics of V-(N, He) composites depend on preliminary treatment of a titanium surface. A coating deposited onto an untreated substrate has specific surface of 25.5 /g. The preliminary irradiation of titanium with beam up to a dose of 6 1017 ion/ provides the increase in surface area up to 57.6 /g. The preliminary ion bombardment provides a considerable increase in hydrogen adsorption capacity of coatings. Especially, such impact is noticeable at the room temperature, when the amount of hydrogen absorbed by a coating that was applied onto a treated surface is more than three times of that absorbed by a coating that was deposited onto nonexposed titanium.

Publisher

Hindawi Limited

Subject

General Materials Science

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