Anodic Dissolution of Spheroidal Graphite Cast Iron with Different Pearlite Areas in Sulfuric Acid Solutions

Author:

Miyata Yoshikazu1,Kuwahara Yuki12,Asakura Shukuji1,Shinohara Tadashi13,Yakou Takao1,Shiimoto Keiichi2

Affiliation:

1. Graduate School of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan

2. Hinode Suido, Ltd., 5-8-18 Katakasu, Hakata-ku, Fukuoka 812-8636, Japan

3. National Institute for Materials Science, 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047, Japan

Abstract

The rate equation of anodic dissolution reaction of spheroidal graphite cast iron in sulfuric acid solutions at 298 K has been studied. The cast irons have different areas of pearlite. The anodic Tafel slope of 0.043 V decade−1and the reaction order with respect to the hydroxyl ion activity of 1 are obtained by the linear potential sweep technique. The anodic current density does not depend on the area of pearlite. There is no difference in the anodic dissolution reaction mechanisms between pure iron and spheroidal graphite cast iron. The anodic current density of the cast iron is higher than that of the pure iron.

Publisher

Hindawi Limited

Subject

Process Chemistry and Technology,General Materials Science

Reference38 articles.

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