Affiliation:
1. Institute for Molecular Science, Okazaki 444, Japan
Abstract
A spectroscopic method has been developed to study chemical reaction processes
through in situ observation of the time profile of molecular absorptions in the millimeter- and
submillimeter-wave regions. The method has been applied to oxidation reactions of
unsaturated hydrocarbons initiated by mercury photosensitization. It has also been
combined with the excimer laser photolysis to examine photodecomposition processes
of SO2, CS2, and Cl2SO, where nascent distributions of photofragments such as SO and
CS were measured. Advantages and disadvantages of the method have been discussed in
some detail.
Subject
Spectroscopy,Biochemistry,Atomic and Molecular Physics, and Optics
Cited by
11 articles.
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