Performance Evaluation of Cyclic Stability and Capacitance of Manganese Oxide Modified Graphene Oxide Nanocomposite for Potential Supercapacitor Applications

Author:

Kumar R. Ranjith1,Thanigaivel S.2,Dey Nibedita2,Priya A. K.3ORCID,Karthick Alagar45ORCID,Mohanavel V.6ORCID,Kannadhasan S.7,Muhibbullah M.8ORCID,Osman Sameh M.9

Affiliation:

1. Department of Civil Engineering, SRM Institute of Science and Technology, NCR Campus, Modinagar, -201204. Uttar Pradesh, Ghaziabad, Delhi, India

2. Saveetha School of Engineering, Department of Biotechnology, Saveetha Institute of Medical and Technical Sciences, Thandalam, 602105, Chennai, Tamil Nadu, India

3. Department of Civil Engineering, KPR Institute of Engineering and Technology, -641407, Coimbatore, Tamilnadu, India

4. Renewable Energy Lab, Department of Electrical and Electronics Engineering, KPR Institute of Engineering and Technology, Coimbatore 641407, Tamil Nadu, India

5. Departamento de Quimica Organica, Universidad de Cordoba, EdificioMarie Curie (C-3), Ctra Nnal IV-A, Km 396, E14014 Cordoba, Spain

6. Chennai-Centre for Materials Engineering and Regenerative Medicine, Bharath Institute of Higher Education and Research, 600073 Tamilnadu, India

7. Department of Electronics and Communication Engineering, Cheran College of Engineering, -639111, Karur, Tamilnadu, India

8. Department of Electrical and Electronic Engineering, Bangladesh University, Dhaka 1207, Bangladesh

9. Chemistry Department, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia

Abstract

Supercapacitors are a revolutionary type of energy storage device. They must be able to charge and discharge quickly while maintaining a high energy density. A storage material’s cyclic stability is a desirable feature. The type of electrode materials employed for the specific study design affects supercapacitor performance. Manganese dioxide has long been regarded as one of the best and most abundant materials in nature, having a potentially high specific capacitance. They also offer a wider potential range, more electroactivity, and are more environmentally friendly. However, because of its decreased volume expansion and low conductivity, it is difficult to use as a capacitor material. As a result, carbon-based porous films and supports can be employed to produce critical composites to overcome the current shortcoming. These nanoparticle-based materials will have improved electrical conductivity and a large surface area. Graphene oxide (GO) has a high surface area, thermal stability, and porosity. As an electrode material, many types of MnO2/carbon-based materials have been widely used in supercapacitors. Their overall performance is influenced by their construction processes, metal ratios, electrolyte medium, and voltage factors. Microwave technology was chosen as a cost-efficient and effective alternative to expensive and laborious techniques for fabricating MnO2/GO composites. The production procedure of a supercapacitor has been explored in this study using MnO2-GO composite materials. Using the electrochemical deposition process, the nanocomposite materials of MnO2-GO are significantly deposited on the stainless steel (SS) substrate material. Galvanostatic charge-discharge techniques and cyclic voltammetry (CV) analytical methods were used to investigate the storage and cycle ability of supercapacitors. The composite MnO2-GO supercapacitor has a higher electrochemical capacitance based on these findings.

Funder

King Saud University

Publisher

Hindawi Limited

Subject

General Materials Science

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