A Study of N,N-Diethylammonium O,O′-Di(p-methoxyphenyl)dithiophosphate as New Corrosion Inhibitor for Carbon Steel in Hydrochloric Acid Solution

Author:

Lai Chuan123,Xie Bin23,Liu Changlu1,Gou Wan1,Zhou Lvshan1,Su Xiulan1,Zou Like23

Affiliation:

1. School of Chemistry and Chemical Engineering, Sichuan University of Arts and Science, Dazhou 635000, China

2. Institute of Functional Materials, Sichuan University of Science and Engineering, Zigong 643000, China

3. Material Corrosion and Protection Key Laboratory of Sichuan Province, Sichuan University of Science and Engineering, Zigong 643000, China

Abstract

N,N-Diethylammonium O,O′-di(p-methoxyphenyl)dithiophosphate (EAPP) as a new corrosion inhibitor was synthesized in the present work. The corrosion inhibition of EAPP in hydrochloric acid for carbon steel was evaluated by potentiodynamic polarization measurements, electrochemical impedance spectroscopy, weight loss measurements, and scanning electron microscopy. The results indicate that the EAPP is mixed type inhibitor, and the adsorption of EAPP on carbon steel surface obeys Langmuir isotherm. In addition, the inhibition efficiency increases with increasing the concentration of inhibitor and decreases with increasing the hydrochloric acid concentration, temperature, and storage time.

Funder

Key Laboratory of Material Corrosion and Protection of Sichuan Province

Publisher

Hindawi Limited

Subject

Process Chemistry and Technology,General Materials Science

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