Multiphoton Ionization of Nitrobenzene in Non-Aqueous Solutions: Characterization of the Cation and Ion-Molecule Chemistry-Reference-Cited by-同舟云学术

Multiphoton Ionization of Nitrobenzene in Non-Aqueous Solutions: Characterization of the Cation and Ion-Molecule Chemistry

Published:1991-01-01 Issue:2 Volume:11 Page:83-93
ISSN:0278-6273
Container-title:Laser Chemistry
language:en
Short-container-title:Laser Chemistry

Author:

Siuzdak G.¹,Belbruno J. J.¹²

Affiliation:

1. Department of Chemistry, Dartmouth College, Hanover 03755, NH, USA

2. Department of Chemistry, Scripps Institute of Medical Research, La Jolla, CA, USA

Abstract

The phenoxy cation has been generated in polar and nonpolar solutions by multiphoton ionization of nitrobenzene using nanosecond pulses of 266 nm and 355 nm light. The ions have been characterized by pulsed conductivity (ion mobility) measurements and transient absorption spectroscopy. The involvement of the phenoxy ion in ion-molecule chemistry with either neutral solute or solvent molecules has also been observed and the photochemical products and quantum yields of the ion-molecule products are presented and compared with the neutral photochemistry results.

Publisher

Hindawi Limited

Subject

Spectroscopy,Biochemistry,Atomic and Molecular Physics, and Optics

Link

http://downloads.hindawi.com/archive/1991/706056.pdf

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