Affiliation:
1. Chemistry Department, Faculty of Applied Science, Umm Al-Qura University, Makah, Saudi Arabia
2. Petrochemicals Department, Egyptian Petroleum Research Institute, Nasr City, Cairo 11727, Egypt
Abstract
Quantitative structure-property relationship (QSPR) is performed as a means to predict octane number of hydrocarbons via correlating properties to parameters calculated from molecular structure; such parameters are molecular mass M, hydration energy EH, boiling point BP, octanol/water distribution coefficient logP, molar refractivity MR, critical pressure CP, critical volume CV, and critical temperature CT. Principal component analysis (PCA) and multiple linear regression technique (MLR) were performed to examine the relationship between multiple variables of the above parameters and the octane number of hydrocarbons. The results of PCA explain the interrelationships between octane number and different variables. Correlation coefficients were calculated using M.S. Excel to examine the relationship between multiple variables of the above parameters and the octane number of hydrocarbons. The data set was split into training of 40 hydrocarbons and validation set of 25 hydrocarbons. The linear relationship between the selected descriptors and the octane number has coefficient of determination (R2=0.932), statistical significance (F=53.21), and standard errors (s =7.7). The obtained QSPR model was applied on the validation set of octane number for hydrocarbons giving RCV2=0.942 and s=6.328.
Cited by
17 articles.
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