Regioselective and Chemoselective Reduction of α,β-Unsaturated Carbonyl Compounds by NaBH4/Ba(OAc)2 as a Reducing System-Reference-Cited by-同舟云学术

Regioselective and Chemoselective Reduction of α,β-Unsaturated Carbonyl Compounds by NaBH4/Ba(OAc)2 as a Reducing System

Published:2013-05-02 Issue: Volume:2013 Page:1-5
ISSN:2090-200X
Container-title:Organic Chemistry International
language:en
Short-container-title:Organic Chemistry International

Author:

Mohamadi Mina¹,Setamdideh Davood¹,Khezri Behrooz¹

Affiliation:

1. Department of Chemistry, Faculty of Sciences, Mahabad Branch, Islamic Azad University, Mahabad 59135-443, Iran

Abstract

α,β-unsaturated aldehydes and ketones are regioselectively reduced to the corresponding allylic alcohols with NaBH4/Ba(OAc)2 system in CH3CN. This system is also efficient for the chemoselective reduction of enals in the presence of enones at room temperature.

Funder

Islamic Azad University

Publisher

Hindawi Limited

Subject

General Earth and Planetary Sciences,General Engineering,General Environmental Science

Link

http://downloads.hindawi.com/archive/2013/127585.pdf

Reference28 articles.

1. Selective Reduction of a, β-Unsaturated Nitrocompounds with Sodium Borohydride in Methanolic Solutions: A Facile Route to Nitroalkenes

2. Use of zinc borohydride as an efficient and highly selective reducing agent. Selective reduction of ketones and conjugated aldehydes over conjugated enones

3. Regioselective 1,2-reduction of conjugated enones and enals with sodium monoacetoxyborohydride: preparation of allylic alcohols