Regioselective and Chemoselective Reduction of α,β-Unsaturated Carbonyl Compounds by NaBH4/Ba(OAc)2 as a Reducing System
Author:
Affiliation:
1. Department of Chemistry, Faculty of Sciences, Mahabad Branch, Islamic Azad University, Mahabad 59135-443, Iran
Abstract
Funder
Islamic Azad University
Publisher
Hindawi Limited
Subject
General Earth and Planetary Sciences,General Engineering,General Environmental Science
Link
http://downloads.hindawi.com/archive/2013/127585.pdf
Reference28 articles.
1. Selective Reduction of a, β-Unsaturated Nitrocompounds with Sodium Borohydride in Methanolic Solutions: A Facile Route to Nitroalkenes
2. Use of zinc borohydride as an efficient and highly selective reducing agent. Selective reduction of ketones and conjugated aldehydes over conjugated enones
3. Regioselective 1,2-reduction of conjugated enones and enals with sodium monoacetoxyborohydride: preparation of allylic alcohols
4. 9-Borabicyclo[3.3.1]nonane as a highly selective reducing agent for the facile conversion of .alpha.,.beta.-unsaturated aldehydes and ketones to the corresponding allylic alcohols in the presence of other functional groups
5. Selective reductions. 22. Facile reduction of .alpha.,.beta.-unsaturated aldehydes and ketones with 9-borabicyclo[3.3.1]nonane. A remarkably convenient procedure for the selective conversion of conjugated aldehydes and ketones to the corresponding allylic alcohols in the presence of other functional groups
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