Effect of Plasticizers on Structural and Dielectric Behaviour of [PEO + (NH4)2C4H8(COO)2] Polymer Electrolyte-Reference-Cited by-同舟云学术

Effect of Plasticizers on Structural and Dielectric Behaviour of [PEO + (NH4)2C4H8(COO)2] Polymer Electrolyte

Published:2013-08-06 Issue: Volume:2013 Page:1-12
ISSN:2314-6877
Container-title:Journal of Polymers
language:en
Short-container-title:Journal of Polymers

Author:

Pandey Kamlesh¹^ORCID,Asthana Nidhi¹,Dwivedi Mrigank Mauli¹,Chaturvedi S. K.²

Affiliation:

1. National Center of Experimental Mineralogy and Petrology, University of Allahabad, Allahabad, UP 211002, India

2. Department of Env. Science, Chitrakoot Gramodaya Vishwavidyalay, Chitrakoot, MP 485334, India

Abstract

Improvements in ion transport property of polyethylene-oxide- (PEO-) based polymer electrolytes have been investigated, using different types of plasticizers. The effects of single and coupled plasticizers [i.e., EC, (EC + PC), and (EC + PEG)] on structural and electrical behavior of pristine electrolyte were studied by XRD, SEM technique, and impedance spectroscopy. The electrical conductivity of the best plasticized system was found to be 4 × 10−6 S/cm. Argand plots show dispersive nature of relaxation time or inhomogeneous space charge polarization of plasticized polymer electrolyte.

Funder

Department of Atomic Energy, Government of India

Publisher

Hindawi Limited

Link

http://downloads.hindawi.com/archive/2013/752596.pdf

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